Observation of the non-linear Meissner effect.

A long-standing theoretical prediction is that in clean, nodal unconventional superconductors the magnetic penetration depth λ, at zero temperature, varies linearly with magnetic field. This non-linear Meissner effect is an equally important manifestation of the nodal state as the well studied linear-in-T dependence of λ, but has never been convincingly experimentally observed. Here we present measurements of the nodal superconductors CeCoIn5 and LaFePO which clearly show this non-linear Meissner effect. We further show how the effect of a small dc magnetic field on λ(T) can be used to distinguish gap nodes from non-nodal deep gap minima. Our measurements of KFe2As2 suggest that this material has such a non-nodal state.

The influence of magnetic order on the magnetoresistance anisotropy of Fe1 + δ-x Cu x Te.

We performed resistance measurements on [Formula: see text]Cu x Te with [Formula: see text] in the presence of in-plane applied magnetic fields, revealing a resistance anisotropy that can be induced at a temperature far below the structural and magnetic zero-field transition temperatures. The observed resistance anisotropy strongly depends on the field orientation with respect to the crystallographic axes, as well as on the field-cooling history. Our results imply a correlation between the observed features and the low-temperature magnetic order. Hysteresis in the angle-dependence indicates a strong pinning of the magnetic order within a temperature range that varies with the Cu content. The resistance anisotropy vanishes at different temperatures depending on whether an external magnetic field or a remnant field is present: the closing temperature is higher in the presence of an external field. For [Formula: see text] the resistance anisotropy closes above the structural transition, at the same temperature at which the zero-field short-range magnetic order disappears and the sample becomes paramagnetic. Thus we suggest that under an external magnetic field the resistance anisotropy mirrors the magnetic order parameter. We discuss similarities to nematic order observed in other iron pnictide materials.

Noncoplanar and counterrotating incommensurate magnetic order stabilized by Kitaev interactions in γ-Li(2)IrO(3).

Materials that realize Kitaev spin models with bond-dependent anisotropic interactions have long been searched for, as the resulting frustration effects are predicted to stabilize novel forms of magnetic order or quantum spin liquids. Here, we explore the magnetism of γ-Li(2)IrO(3), which has the topology of a three-dimensional Kitaev lattice of interconnected Ir honeycombs. Using magnetic resonant x-ray diffraction, we find a complex, yet highly symmetric incommensurate magnetic structure with noncoplanar and counterrotating Ir moments. We propose a minimal Kitaev-Heisenberg Hamiltonian that naturally accounts for all key features of the observed magnetic structure. Our results provide strong evidence that γ-Li(2)IrO(3) realizes a spin Hamiltonian with dominant Kitaev interactions.

Distinguishing bulk and surface electron-phonon coupling in the topological insulator Bi(2)Se(3) using time-resolved photoemission spectroscopy.

We report time- and angle-resolved photoemission spectroscopy measurements on the topological insulator Bi(2)Se(3). We observe oscillatory modulations of the electronic structure of both the bulk and surface states at a frequency of 2.23 THz due to coherent excitation of an A(1g) phonon mode. A distinct, additional frequency of 2.05 THz is observed in the surface state only. The lower phonon frequency at the surface is attributed to the termination of the crystal and thus reduction of interlayer van der Waals forces, which serve as restorative forces for out-of-plane lattice distortions. Density functional theory calculations quantitatively reproduce the magnitude of the surface phonon softening. These results represent the first band-resolved evidence of the A(1g) phonon mode coupling to the surface state in a topological insulator.

Direct optical coupling to an unoccupied dirac surface state in the topological insulator Bi2Se3.

We characterize the occupied and unoccupied electronic structure of the topological insulator Bi2Se3 by one-photon and two-photon angle-resolved photoemission spectroscopy and slab band structure calculations. We reveal a second, unoccupied Dirac surface state with similar electronic structure and physical origin to the well-known topological surface state. This state is energetically located 1.5 eV above the conduction band, which permits it to be directly excited by the output of a Ti:sapphire laser. This discovery demonstrates the feasibility of direct ultrafast optical coupling to a topologically protected, spin-textured surface state.

Unconventional Josephson effect in hybrid superconductor-topological insulator devices.

We report on transport properties of Josephson junctions in hybrid superconducting-topological insulator devices, which show two striking departures from the common Josephson junction behavior: a characteristic energy that scales inversely with the width of the junction, and a low characteristic magnetic field for suppressing supercurrent. To explain these effects, we propose a phenomenological model which expands on the existing theory for topological insulator Josephson junctions.

STM imaging of impurity resonances on Bi2Se3.

In this Letter we present detailed study of the density of states near defects in Bi2Se3. In particular, we present data on the commonly found triangular defects in this system. While we do not find any measurable quasiparticle scattering interference effects, we do find localized resonances, which can be well fitted by theory [R. R. Biswas and A. V. Balatsky, Phys. Rev. B 81, 233405(R) (2010)] once the potential is taken to be extended to properly account for the observed defects. The data together with the fits confirm that while the local density of states around the Dirac point of the electronic spectrum at the surface is significantly disrupted near the impurity by the creation of low-energy resonance state, the Dirac point is not locally destroyed. We discuss our results in terms of the expected protected surface state of topological insulators.

Ultrafast optical excitation of a persistent surface-state population in the topological insulator Bi2Se3.

Using femtosecond time- and angle-resolved photoemission spectroscopy, we investigated the nonequilibrium dynamics of the topological insulator Bi2Se3. We studied p-type Bi2Se3, in which the metallic Dirac surface state and bulk conduction bands are unoccupied. Optical excitation leads to a metastable population at the bulk conduction band edge, which feeds a nonequilibrium population of the surface state persisting for >10 ps. This unusually long-lived population of a metallic Dirac surface state with spin texture may present a channel in which to drive transient spin-polarized currents.

Massive Dirac fermion on the surface of a magnetically doped topological insulator.

In addition to a bulk energy gap, topological insulators accommodate a conducting, linearly dispersed Dirac surface state. This state is predicted to become massive if time reversal symmetry is broken, and to become insulating if the Fermi energy is positioned inside both the surface and bulk gaps. We introduced magnetic dopants into the three-dimensional topological insulator dibismuth triselenide (Bi2Se3) to break the time reversal symmetry and further position the Fermi energy inside the gaps by simultaneous magnetic and charge doping. The resulting insulating massive Dirac fermion state, which we observed by angle-resolved photoemission, paves the way for studying a range of topological phenomena relevant to both condensed matter and particle physics.

STM imaging of electronic waves on the surface of Bi2Te3: topologically protected surface states and hexagonal warping effects.

Scanning tunneling spectroscopy studies on high-quality Bi2Te3 crystals exhibit perfect correspondence to angle-resolved photoemission spectroscopy data, hence enabling identification of different regimes measured in the local density of states (LDOS). Oscillations of LDOS near a step are analyzed. Within the main part of the surface band oscillations are strongly damped, supporting the hypothesis of topological protection. At higher energies, as the surface band becomes concave, oscillations appear, dispersing with a wave vector that may result from a hexagonal warping term.

Single Dirac cone topological surface state and unusual thermoelectric property of compounds from a new topological insulator family.

Angle resolved photoemission spectroscopy study on TlBiTe2 and TlBiSe2 from a thallium-based ternary chalcogenides family revealed a single surface Dirac cone at the center of the Brillouin zone for both compounds. For TlBiSe2, the large bulk gap (∼200 meV) makes it a topological insulator with better mechanical properties than the previous binary 3D topological insualtor family. For TlBiTe2, the observed negative bulk gap indicates it as a semimetal, instead of a narrow-gap semiconductor as conventionally believed; this semimetality naturally explains its mysteriously small thermoelectric figure of merit comparing to other compounds in the family. Finally, the unique band structures of TlBiTe2 also suggest it as a candidate for topological superconductors.

Enhanced Fermi-surface nesting in superconducting BaFe2(As(1-x)P(x))2 revealed by the de Haas-van Alphen effect.

The three-dimensional Fermi-surface morphology of superconducting BaFe2(As0.37P0.63)2 with T(c)=9 K is determined using the de Haas-van Alphen effect. The inner electron pocket has a similar area and k(z) interplane warping to the observed hole pocket, revealing that the Fermi surfaces are geometrically well nested in the (π,π) direction. These results are in stark contrast to the fermiology of the nonsuperconducting phosphides (x=1), and therefore suggest an important role for nesting in pnictide superconductivity.

Fermi surface of SrFe2P2 determined by the de Haas-van Alphen effect.

We report measurements of the Fermi surface (FS) of the ternary iron-phosphide SrFe2P2 using the de Haas-van Alphen effect. The calculated FS of this compound is very similar to SrFe2As2, the parent compound of the high temperature superconductors. Our data show that the Fermi surface is composed of two electron and two hole sheets in agreement with band-structure calculations. Several of the sheets show strong c-axis warping emphasizing the importance of three dimensionality in the nonmagnetic state of the ternary pnictides. We find that the electron and hole pockets have a different topology, implying that this material does not satisfy a (pi, pi) nesting condition.

Topological change of the Fermi surface in ternary iron pnictides with reduced c/a ratio: a de Haas-van Alphen study of CaFe2P2.

We report a de Haas-van Alphen effect study of the Fermi surface of CaFe2P2 using low-temperature torque magnetometry up to 45 T. This system is a close structural analog of the collapsed tetragonal nonmagnetic phase of CaFe2As2. We find the Fermi surface of CaFe2P2 to differ from other related ternary phosphides in that its topology is highly dispersive in the c axis, being three dimensional in character and with identical mass enhancement on both electron and hole pockets ( approximately 1.5). This suggests that when the bonding between pnictogen layers becomes important nesting conditions are not fulfilled.

Experimental realization of a three-dimensional topological insulator, Bi2Te3.

Three-dimensional topological insulators are a new state of quantum matter with a bulk gap and odd number of relativistic Dirac fermions on the surface. By investigating the surface state of Bi2Te3 with angle-resolved photoemission spectroscopy, we demonstrate that the surface state consists of a single nondegenerate Dirac cone. Furthermore, with appropriate hole doping, the Fermi level can be tuned to intersect only the surface states, indicating a full energy gap for the bulk states. Our results establish that Bi2Te3 is a simple model system for the three-dimensional topological insulator with a single Dirac cone on the surface. The large bulk gap of Bi2Te3 also points to promising potential for high-temperature spintronics applications.

Directional field-induced metallization of quasi-one-dimensional Li0.9Mo6O17.

We report a detailed magnetotransport study of the highly anisotropic quasi-one-dimensional oxide Li(0.9)Mo(6)O(17) whose in-chain electrical resistivity diverges below a temperature T_{min} approximately 25 K. For T < T_{min}, a magnetic field applied parallel to the conducting chain induces a large negative magnetoresistance and, ultimately, the recovery of a metallic state. We show evidence that this insulator-metal crossover is a consequence of field-induced suppression of a density-wave gap in a highly one-dimensional conductor. At the highest fields studied, there is evidence for the possible emergence of a novel superconducting state with an onset temperature T_{c} > 10 K.

Evidence for a nodal-line superconducting state in LaFePO.

In several iron-arsenide superconductors there is strong evidence for a fully gapped superconducting state consistent with either a conventional s-wave symmetry or an unusual s{+/-} state where the gap changes sign between the electron and hole Fermi-surface sheets. Here we report measurements of the penetration depth lambda(T) in very clean samples of the related iron-phosphide superconductor, LaFePO, at temperatures down to approximately 100 mK. We find that lambda(T) varies approximately linearly with T strongly suggesting the presence of gap nodes in this compound. Taken together with other data, this suggests the gap function is not universal for all pnictide superconductors.

Fermi surface of superconducting LaFePO determined from quantum oscillations.

We report extensive measurements of quantum oscillations in the normal state of the Fe-based superconductor LaFePO, (T(c) approximately 6 K) using low temperature torque magnetometry and transport in high static magnetic fields (45 T). We find that the Fermi surface is in broad agreement with the band-structure calculations with the quasiparticle mass enhanced by a factor approximately 2. The quasi-two-dimensional Fermi surface consists of nearly nested electron and hole pockets, suggesting proximity to a spin or charge density wave instability.

Correlation between the superconducting transition temperature and anisotropic quasiparticle scattering in Tl2Ba2CuO6+delta.

Angle-dependent magnetoresistance measurements are used to determine the isotropic and anisotropic components of the transport scattering rate in overdoped Tl2Ba2CuO6+delta for a range of Tc values between 15 and 35 K. The size of the anisotropic scattering term is found to scale linearly with Tc, establishing a link between the superconducting and normal state physics. A comparison with results from angle resolved photoemission spectroscopy indicates that the transport and quasiparticle lifetimes are distinct.

Shubnikov-de Haas effect in the metallic state of Na0.3CoO2.

Shubnikov-de Haas oscillations for two well-defined frequencies, corresponding, respectively, to areas of 0.8 and 1.36% of the first Brillouin zone, were observed in single crystals of Na(0.3)CoO2. The existence of Na superstructures in Na0.3CoO2, coupled with this observation, suggests the possibility that the periods are due to the reconstruction of the large Fermi surface around the Gamma point. An alternative interpretation in terms of the long sought-after epsilon'(g) pockets is also considered but found to be incompatible with existing specific heat data.